Bulk rheology characterization of biopolymer solutions and discussions of their potential for enhanced oil recovery applications

  • Karl Jan Clinckspoor Laboratory for Oil Reservoirs, Mechanical Engineering School, University of Campinas (UNICAMP), Campinas, Brazil https://orcid.org/0000-0002-0916-2773
  • Vitor Hugo de Sousa Ferreira Laboratory for Oil Reservoirs, Mechanical Engineering School, University of Campinas (UNICAMP), Campinas, Brazil https://orcid.org/0000-0002-8789-0741
  • Rosangela Barros Zanoni Lopes Moreno Energy Department, Mechanical Engineering School, Laboratory for Oil Reservoirs, Mechanical Engineering School, University of Campinas (UNICAMP), Campinas, Brazil https://orcid.org/0000-0001-5216-4638
Keywords: Biopolymer, Rheology, Enhanced Oil recovery, Polymer Flooding

Abstract

Enhanced oil recovery (EOR) techniques are essential to improve oil production, and polymer flooding has become one of the promising technologies for the Brazilian Pre-Salt scenario. Biopolymers offer a range of advantages considering the Pre-Salt conditions compared to synthetic polymers, such as resistance to high salinity, high temperature, and mechanical degradation. In that sense, bulk rheology is the first step in a workflow for performance analysis.

This paper presents a rheological analysis of four biopolymers (Schizophyllan, Scleroglucan, Guar Gum, and Xanthan Gum) in concentrations from 10 to 2,300 ppm, generally suitable for EOR applications, in temperature levels of 25, 40, 50, 60 and 70°C and two brines of 30,100 ppm and 69,100 ppm total dissolved solids, which aim to model seawater and the mixture between injected seawater and reservoir water typical in Pre-Salt conditions. The pseudoplastic behavior, the overlap concentration, and the activation energy were determined for each polymer solution.

The structural differences in the polymers resulted in different rheological behaviors. Schizophyllan is the most promising, as its viscosifying power is higher than synthetic polymers comparable to Xanthan Gum.  Its resistance at high temperatures is higher than that of synthetic polymers. Scleroglucan behaved similarly to Xanthan Gum, with the added advantage of being nonionic. Guar Gum had the lowest viscosities, highest overlap concentrations, and most pronounced viscosity decay among the tested polymers.

To the author’s knowledge, rheological studies of the biopolymers presented here, considering the viscosities and the overlap concentration and activation energy, in the Pre-salt conditions, are not available in the literature and this will benefit future works that depend on this information

References

E. Walid Al Shalabi and K. Sepehrnoori, "Introduction to Enhanced Oil Recovery Processes," in Low Salinity and Engineered Water Injection for Sandstone and Carbonate Reservoirs, E. Walid Al Shalabi and K. Sepehrnoori, Eds. Elsevier, 2017, p. Chap. 1, 1-5. https://doi.org/10.1016/B978-0-12-813604-1.00001-8

K. S. Sorbie, Polymer-Improved Oil Recovery. Dordrecht: Springer Netherlands, 1991. https://doi.org/10.1007/978-94-011-3044-8.

J. Sheng, Modern chemical enhanced oil recovery: theory and practice. Burlington, MA, USA: Gulf Professional Pub, 2011.

E. C. Donaldson and R. D. Thomas, "Microscopic Observations of Oil Displacement in Water-Wet and Oil-Wet Systems," presented at the Fall Meeting of the Society of Petroleum Engineers of AIME, New Orleans, Louisiana, 1971. https://doi.org/10.2118/3555-MS

S. Doorwar and K. K. Mohanty, "Polymer Flood of Viscous Oils in Complex Carbonates," presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 2014. https://doi.org/10.2118/169162-MS

H. Saboorian-Jooybari, M. Dejam, and Z. Chen, "Heavy oil polymer flooding from laboratory core floods to pilot tests and field applications: Half-century studies," Journal of Petroleum Science and Engineering, vol. 142, pp. 85-100, Jun. 2016. https://doi.org/10.1016/j.petrol.2016.01.023.

J. J. Taber and F. D. Martin, "Technical Screening Guides for the Enhanced Recovery of Oil," 1983, p. 20. https://doi.org/10.2118/12069-MS

L. W. Lake, Enhanced oil recovery. Englewood Cliffs, N.J: Prentice Hall, 1989.

J. J. Sheng, B. Leonhardt, and N. Azri, "Status of Polymer-Flooding Technology," Journal of Canadian Petroleum Technology, vol. 54, no. 02, pp. 116-126, Mar. 2015.

https://doi.org/10.2118/174541-PA.

W. Littmann, Polymer flooding. Amsterdam: Elsevier, 1988.

D. J. Pye, "Improved Secondary Recovery by Control of Water Mobility," Journal of Petroleum Technology, vol. 16, no. 08, pp. 911-916, Aug. 1964. https://doi.org/10.2118/845-PA

B. B. Sandiford, "Laboratory and Field Studies of Water Floods Using Polymer Solutions to Increase Oil Recoveries," Journal of Petroleum Technology, vol. 16, no. 08, pp. 917-922, Aug. 1964. https://doi.org/10.2118/844-PA.

E. Delamaide, "Polymer Flooding of Heavy Oil - From Screening to Full-Field Extension," presented at the SPE Heavy and Extra Heavy Oil Conference: Latin America, Medellín, Colombia, 2014. https://doi.org/10.2118/171105-MS

L. D. Saleh, M. Wei, and B. Bai, "Data Analysis and Updated Screening Criteria for Polymer Flooding Based on Oilfield Data," SPE Reservoir Evaluation & Engineering, vol. 17, no. 01, pp. 15-25, Feb. 2014. https://doi.org/10.2118/168220-PA

W. Pu, C. Shen, B. Wei, Y. Yang, and Y. Li, "A comprehensive review of polysaccharide biopolymers for enhanced oil recovery (EOR) from flask to field," Journal of Industrial and Engineering Chemistry, vol. 61, pp. 1-11, May 2018. https://doi.org/10.1016/j.jiec.2017.12.034

K. Liang, P. Han, Q. Chen, X. Su, and Y. Feng, "Comparative Study on Enhancing Oil Recovery under High Temperature and High Salinity: Polysaccharides Versus Synthetic Polymer," ACS Omega, vol. 4, no. 6, pp. 10620-10628, Jun. 2019. https://doi.org/10.1021/acsomega.9b00717

B. Wei, L. Romero-Zerón, and D. Rodrigue, "Mechanical Properties and Flow Behavior of Polymers for Enhanced Oil Recovery," Journal of Macromolecular Science, Part B, vol. 53, no. 4, pp. 625-644, Apr. 2014. https://doi.org/10.1080/00222348.2013.857546

R. H. Castro García, S. Llanos Gallo, J. L. Rodriguez Ardila, H. I. Quintero Pérez, E. J. Manrique Ventura, and J. F. Zapata Arango, "Heavy Oil and High-Temperature Polymer EOR Applications," CT&F Cienc. Tecnol. Futuro, vol. 10, no. 2, pp. 73-83, Dec. 2020. https://doi.org/10.29047/01225383.258

V. H. S. Ferreira and R. B. Z. L. Moreno, "Workflow for Oil Recovery Design by Polymer Flooding," in Volume 8: Polar and Arctic Sciences and Technology; Petroleum Technology, Madrid, Spain, Jun. 2018, p. V008T11A045. https://doi.org/10.1115/OMAE2018-78359

M. H. Akstinat, "Polymers For Enhanced Oil Recovery In Reservoirs Of Extremely High Salinities And High Temperatures," California, 1980, pp. 33-45. https://doi.org/10.2118/8979-MS

R. S. Seright, "How Much Polymer Should Be Injected During a Polymer Flood? Review of Previous and Current Practices," SPE Journal, vol. 22, no. 01, pp. 1-18, Feb. 2017. https://doi.org/10.2118/179543-PA

D. C. Standnes and I. Skjevrak, "Literature review of implemented polymer field projects," Journal of Petroleum Science and Engineering, vol. 122, pp. 761-775, Oct. 2014. https://doi.org/10.1016/j.petrol.2014.08.024

P.-S. Kang, J.-S. Lim, and C. Huh, "Screening Criteria and Considerations of Offshore Enhanced Oil Recovery," Energies, vol. 9, no. 1, p. 44, Jan. 2016. https://doi.org/10.3390/en9010044

W. Graessley, "Polymer chain dimensions and the dependence of viscoelastic properties on concentration, molecular weight and solvent power," Polymer, vol. 21, no. 3, pp. 258-262, Mar. 1980. https://doi.org/10.1016/0032-3861(80)90266-9

G. Chauveteau, "Rodlike Polymer Solution Flow through Fine Pores: Influence of Pore Size on Rheological Behavior," Journal of Rheology, vol. 26, no. 2, pp. 111-142, 1982. https://doi.org/10.1122/1.549660

P. G. de Gennes, Scaling concepts in polymer physics. Ithaca, N.Y: Cornell University Press, 1979.

V. H. S. Ferreira and R. B. Z. L. Moreno, "Polyacrylamide Adsorption and Readsorption in Sandstone Porous Media," SPE Journal, vol. 25, no. 01, pp. 497-514, Feb. 2020. https://doi.org/10.2118/199352-PA

G. Zhang and R. Seright, "Effect of Concentration on HPAM Retention in Porous Media," SPE Journal, vol. 19, no. 03, pp. 373-380, Jun. 2014. https://doi.org/10.2118/166265-PA

W.-M. Kulicke and C. Clasen, Viscosimetry of polymers and polyelectrolytes. Berlin ; New York: Springer, 2004. https://doi.org/10.1007/978-3-662-10796-6

H. Eyring, "Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates," The Journal of Chemical Physics, vol. 4, no. 4, pp. 283-291, Apr. 1936. https://doi.org/10.1063/1.1749836

N. Hirai and H. Eyring, "Bulk viscosity of polymeric systems," Journal of Polymer Science, vol. 37, no. 131, pp. 51-70, May 1959. https://doi.org/10.1002/pol.1959.1203713104

Y. Lou, Q. Lei, and G. Wu, "Research on Polymer Viscous Flow Activation Energy and Non-Newtonian Index Model Based on Feature Size," Advances in Polymer Technology, vol. 2019, pp. 1-11, May 2019. https://doi.org/10.1155/2019/1070427

P. B. Macedo and T. A. Litovitz, "On the Relative Roles of Free Volume and Activation Energy in the Viscosity of Liquids," The Journal of Chemical Physics, vol. 42, no. 1, pp. 245-256, Jan. 1965. https://doi.org/10.1063/1.1695683

H. D. Chandler, "A physical basis for non-Newtonian power-law viscosity," Soft Materials, vol. 17, no. 2, pp. 137-142, Apr. 2019. https://doi.org/10.1080/1539445X.2019.1568262.

M. R. V. de Moura and R. B. Z. L. Moreno, "Concentration, Brine Salinity and Temperature effects on Xanthan Gum Solutions Rheology," Applied Rheology, vol. 29, no. 1, pp. 69-79, Jan. 2019. https://doi.org/10.1515/arh-2019-0007

W. R. Moore and A. M. Brown, "Viscosity-temperature relationships for dilute solutions of cellulose derivatives," Journal of Colloid Science, vol. 14, no. 1, pp. 1-12, Feb. 1959. https://doi.org/10.1016/0095-8522(59)90064-9

I. R. Raupov and G. Yurevich, "Research of polymer compositions rheological properties for oil production," Acta Technica CSAV (Ceskoslovensk Akademie Ved), vol. 63, no. 3, pp. 493-500, 2018. [Online]. Available. http://journal.it.cas.cz/63(2018)-1B/Paper%20D-07%20Raupov.pdf

D. R. Rohindra, R. A. Lata, and R. K. Coll, "A simple experiment to determine the activation energy of the viscous flow of polymer solutions using a glass capillary viscometer," Eur. J. Phys., vol. 33, no. 5, pp. 1457-1464, Sep. 2012. https://doi.org/10.1088/0143-0807/33/5/1457

E. J. R. Rueda and R. B. Z. L. Moreno, "Polymer concentration, brine salinity and temperature effects on xanthan gum solutions rheology - a complementary and check-up study," Uberlândia, 2019, p. 10. https://doi.org/10.26678/ABCM.COBEM2019.COB2019-2215

B. Kronberg, K. Holmberg, and B. Lindman, Surface chemistry of surfactants and polymers. Chichester, West Sussex: Wiley, 2014. https://doi.org/10.1002/9781118695968.

J. N. Israelachvili, Intermolecular and surface forces, Third. Amsterdam: Elsevier, Academic Press, 2011.

G. Chauveteau and N. Kohler, "Influence of Microgels in Polysaccharide Solutions on Their Flow Behavior Through Porous Media," Society of Petroleum Engineers Journal, vol. 24, no. 03, pp. 361-368, Jun. 1984. https://doi.org/10.2118/9295-PA

P. Davison and E. Mentzer, "Polymer Flooding in North Sea Reservoirs," Society of Petroleum Engineers Journal, vol. 22, no. 03, pp. 353-362, Jun. 1982. https://doi.org/10.2118/9300-PA

M. Al-Saleh, A. Yussuf, M. Jumaa, A. Hammoud, and T. Al-Shammari, "Biopolymer Solution Evaluation Methodology: Thermal and Mechanical Assessment for Enhanced Oil Recovery with High Salinity Brines," Processes, vol. 7, no. 6, pp. 1-13, Jun. 2019. https://doi.org/10.3390/pr7060339

R. C. Rivenq, A. Donche, and C. Nolk, "Improved Scleroglucan for Polymer Flooding Under Harsh Reservoir Conditions," SPE Reservoir Engineering, vol. 7, no. 01, pp. 15-20, Feb. 1992. https://doi.org/10.2118/19635-PA

S. A. Frangou, E. R. Morris, D. A. Rees, R. K. Richardson, and S. B. Ross-Murphy, "Molecular origin of xanthan solution rheology: Effect of urea on chain conformation and interactions," Journal of Polymer Science: Polymer Letters Edition, vol. 20, no. 10, pp. 531-538, Oct. 1982. https://doi.org/10.1002/pol.1982.130201004.

M. Milas and M. Rinaudo, "Conformational investigation on the bacterial polysaccharide xanthan," Carbohydrate Research, vol. 76, no. 1, pp. 189-196, Nov. 1979. https://doi.org/10.1016/0008-6215(79)80017-8

U. Rau, R.-J. Müller, K. Cordes, and J. Klein, "Process and molecular data of branched 1,3-β-D-glucans in comparison with Xanthan," Bioprocess Engineering, vol. 5, no. 2, pp. 89-93, 1990. https://doi.org/10.1007/BF00589151

P. F. de J. Cano-Barrita and F. M. León-Martínez, "Biopolymers with viscosity-enhancing properties for concrete," in Biopolymers and Biotech Admixtures for Eco-Efficient Construction Materials, F. Pacheco-Torgal, V. Ivanov, N. Karak, and H. Jonkers, Eds. Duxford, UK: Woodhead Publishing, 2016, pp. 221-252. https://doi.org/10.1016/B978-0-08-100214-8.00011-7

T. L. Bluhm, Y. Deslandes, R. H. Marchessault, S. Pérez, and M. Rinaudo, "Solid-state and solution conformation of scleroglucan," Carbohydrate Research, vol. 100, no. 1, pp. 117-130, 1982. https://doi.org/10.1016/S0008-6215(00)81030-7

M. J. Gidley and K. Nishinari, "Physico-chemistry of (1,3)-β-Glucans," in Chemistry, Biochemistry, and Biology of (1→3)-β-Glucans and Related Polysaccharides, Elsevier, 2009, pp. 47-118. https://doi.org/10.1016/B978-0-12-373971-1.00003-0

J. Schmid, V. Meyer, and V. Sieber, "Scleroglucan: biosynthesis, production and application of a versatile hydrocolloid," Appl Microbiol Biotechnol, vol. 91, no. 4, pp. 937-947, Aug. 2011. https://doi.org/10.1007/s00253-011-3438-5

T. Yanaki, T. Kojima, and T. Norisuye, "Triple Helix of Scleroglucan in Dilute Aqueous Sodium Hydroxide," Polymer Journal, vol. 13, no. 12, pp. 1135-1143, Dec. 1981. https://doi.org/10.1295/polymj.13.1135.

Y. Fang, R. Takahashi, and K. Nishinari, "Rheological characterization of schizophyllan aqueous solutions after denaturation-renaturation treatment," Biopolymers, vol. 74, no. 4, pp. 302-315, Jul. 2004. https://doi.org/10.1002/bip.20081.

D. Lecacheux, Y. Mustiere, R. Panaras, and G. Brigand, "Molecular weight of scleroglucan and other extracellular microbial polysaccharides by size-exclusion chromatography and low angle laser light scattering," Carbohydrate Polymers, vol. 6, no. 6, pp. 477-492, Jan. 1986. https://doi.org/10.1016/0144-8617(86)90005-6

T. Norisuye, T. Yanaki, and H. Fujita, "Triple helix of a schizophyllum commune polysaccharide in aqueous solution," Journal of Polymer Science: Polymer Physics Edition, vol. 18, pp. 547-558, Mar. 1980. https://doi.org/10.1002/pol.1980.180180314

S. C. Viñarta, O. D. Delgado, L. I. C. Figueroa, and J. I. Fariña, "Effects of thermal, alkaline and ultrasonic treatments on scleroglucan stability and flow behavior," Carbohydrate Polymers, vol. 94, no. 1, pp. 496-504, Apr. 2013. https://doi.org/10.1016/j.carbpol.2013.01.063

Y. Wang and B. McNeil, "Scleroglucan," Critical Reviews in Biotechnology, vol. 16, no. 3, pp. 185-215, Jan. 1996. https://doi.org/10.3109/07388559609147421

T. Itou, A. Teramoto, T. Matsuo, and H. Suga, "Isotope effect on the order-disorder transition in aqueous schizophyllan," Carbohydrate Research, vol. 160, pp. 243-257, Feb. 1987. https://doi.org/10.1016/0008-6215(87)80315-4

J. L. Doublier and B. Launay, "Rheology of Galactomannan Solutions: Comparative Study of Guar Gum and Locust Bean Gum," Journal of Texture Studies, vol. 12, no. 2, pp. 151-172, Jun. 1981. https://doi.org/10.1111/j.1745-4603.1981.tb01229.x

D. Szopinski, W.-M. Kulicke, and G. A. Luinstra, "Structure-property relationships of carboxymethyl hydroxypropyl guar gum in water and a hyperentanglement parameter," Carbohydrate Polymers, vol. 119, pp. 159-166, Mar. 2015. https://doi.org/10.1016/j.carbpol.2014.11.050

N. Lucyszyn, "Aplicação de galactomananas como substitutas parciais do ágar no cultivo de tecidos vegetais (Application of galactomannans as partial substitutes of agar in the cultivation of vegetable tissue)," PhD Thesis, Universidade Federal do Paraná, Curitiba, Paraná, 2004. [Online]. Available: https://hdl.handle.net/1884/28026

D. Szopinski, U. A. Handge, W.-M. Kulicke, V. Abetz, and G. A. Luinstra, "Extensional flow behavior of aqueous guar gum derivative solutions by capillary breakup elongational rheometry (CaBER)," Carbohydrate Polymers, vol. 136, pp. 834-840, Jan. 2016. https://doi.org/10.1016/j.carbpol.2015.09.067

B. Launay, G. Cuvelier, and S. Martinez-Reyes, "Viscosity of locust bean, guar and xanthan gum solutions in the Newtonian domain: a critical examination of the log (ηsp)o-log C[η]o master curves," Carbohydrate Polymers, vol. 34, no. 4, pp. 385-395, Dec. 1997. https://doi.org/10.1016/S0144-8617(97)00104-5

V. P. Kapoor, M. Milas, F. R. Taravel, and M. Rinaudo, "Rheological properties of seed galactomannan from Cassia nodosa buch.-hem.," Carbohydrate Polymers, vol. 25, no. 2, pp. 79-84, Jan. 1994. https://doi.org/10.1016/0144-8617(94)90142-2

R. H. W. Wientjes, M. H. G. Duits, R. J. J. Jongschaap, and J. Mellema, "Linear Rheology of Guar Gum Solutions," Macromolecules, vol. 33, no. 26, pp. 9594-9605, Dec. 2000. https://doi.org/10.1021/ma001065p

G. Robinson, S. B. Ross-Murphy, and E. R. Morris, "Viscosity-molecular weight relationships, intrinsic chain flexibility, and dynamic solution properties of guar galactomannan," Carbohydrate Research, vol. 107, no. 1, pp. 17-32, Sep. 1982. https://doi.org/10.1016/S0008-6215(00)80772-7

M. S. Celik, S. Ahmad, and H. S. Al-Hashim, "Adsorption/desorption of polymers from Saudi Arabian limestone," Journal of Petroleum Science and Engineering, vol. 6, no. 3, pp. 213-223, Nov. 1991. https://doi.org/10.1016/0920-4105(91)90014-E

R. Fournier, J.-E. Tiehi, and A. Zaitoun, "Laboratory Study of a New EOR-Grade Scleroglucan," presented at the SPE EOR Conference at Oil and Gas West Asia, Muscat, Oman, 2018. https://doi.org/10.2118/190451-MS.

F. D. Martin, M. J. Hatch, J. S. Shepitka, and J. S. Ward, "Improved Water-Soluble Polymers for Enhanced Recovery of Oil," Denver, Colorado, USA, 1983, pp. 151-164. https://doi.org/10.2118/11786-MS.

E. U. Kulawardana et al., "Rheology and Transport of Improved EOR Polymers under Harsh Reservoir Conditions," presented at the SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 2012. https://doi.org/10.2118/154294-MS.

F. R. P. Mansoldo et al., "Quantification of schizophyllan directly from the fermented broth by ATR-FTIR and PLS regression," Anal. Methods, p. 10.1039.D0AY01585G, Issue 45, 2020. https://doi.org/10.1039/D0AY01585G

American Petroleum Institute, Recommended Practices for Evaluation of Polymers Used in Enhanced Oil Recovery Operations (API RP 63), 1990.

T. W. Abraham and E. S. Sumner, "Method for solubilizing biopolymer solids for enhanced oil recovery applications," US 2019/0112518A1, Apr. 18, 2019

R. H. Ewoldt, M. T. Johnston, and L. M. Caretta, "Experimental Challenges of Shear Rheology: How to Avoid Bad Data," in Complex Fluids in Biological Systems, S. E. Spagnolie, Ed. New York, NY: Springer, 2015, pp. 207-241. [Online]. Available: http://link.springer.com/10.1007/978-1-4939-2065-5_6

A. Samanta, K. Ojha, and A. Mandal, "The Characterization of Natural Surfactant and Polymer and Their Use in Enhanced Recovery of Oil," Petroleum Science and Technology, vol. 29, no. 7, pp. 765-777, Feb. 2011. https://doi.org/10.1080/10916460903485819

M. Sveistrup, F. van Mastrigt, J. Norrman, F. Picchioni, and K. Paso, "Viability of Biopolymers for Enhanced Oil Recovery," Journal of Dispersion Science and Technology, vol. 37, no. 8, pp. 1160-1169, Aug. 2016. https://doi.org/10.1080/01932691.2015.1088450

M. S. Kamal, A. S. Sultan, U. A. Al-Mubaiyedh, and I. A. Hussein, "Review on Polymer Flooding: Rheology, Adsorption, Stability, and Field Applications of Various Polymer Systems," Polymer Reviews, vol. 55, no. 3, pp. 491-530, Jul. 2015. https://doi.org/10.1080/15583724.2014.982821

B. T. Stokke, A. Elgsaeter, E. Ø. Bjørnestad, and T. Lund, "Rheology of xanthan and scleroglucan in synthetic seawater," Carbohydrate Polymers, vol. 17, no. 3, pp. 209-220, Jan. 1992. https://doi.org/10.1016/0144-8617(92)90006-C

G. Cuvelier and B. Launay, "Concentration regimes in xanthan gum solutions deduced from flow and viscoelastic properties," Carbohydrate Polymers, vol. 6, no. 5, pp. 321-333, Jan. 1986. https://doi.org/10.1016/0144-8617(86)90023-8

M. Milas, M. Rinaudo, M. Knipper, and J. L. Schuppiser, "Flow and viscoelastic properties of xanthan gum solutions," Macromolecules, vol. 23, no. 9, pp. 2506-2511, Apr. 1990. https://doi.org/10.1021/ma00211a018

E. L. Meyer, G. G. Fuller, R. C. Clark, and W. M. Kulicke, "Investigation of xanthan gum solution behavior under shear flow using rheooptical techniques," Macromolecules, vol. 26, no. 3, pp. 504-511, May 1993. https://doi.org/10.1021/ma00055a016

A. B. Rodd, D. E. Dunstan, and D. V. Boger, "Characterisation of xanthan gum solutions using dynamic light scattering and rheology," Carbohydrate Polymers, vol. 42, no. 2, pp. 159-174, Jun. 2000. https://doi.org/10.1016/S0144-8617(99)00156-3

N. B. Wyatt and M. W. Liberatore, "Rheology and viscosity scaling of the polyelectrolyte xanthan gum," J. Appl. Polym. Sci., vol. 114, no. 6, pp. 4076-4084, Dec. 2009. https://doi.org/10.1002/app.31093

Z. V. Baines and E. R. Morris, "Flavour/taste perception in thickened systems: the effect of guar gum above and below c*," Food Hydrocolloids, vol. 1, no. 3, pp. 197-205, Apr. 1987. https://doi.org/10.1016/S0268-005X(87)80003-6

E. R. Morris, A. N. Cutler, S. B. Ross-Murphy, D. A. Rees, and J. Price, "Concentration and shear rate dependence of viscosity in random coil polysaccharide solutions," Carbohydrate Polymers, vol. 1, no. 1, pp. 5-21, Sep. 1981. https://doi.org/10.1016/0144-8617(81)90011-4

Y. Kashiwagi, T. Norisuye, and H. Fujita, "Triple helix of Schizophyllum commune polysaccharide in dilute solution. 4. Light scattering and viscosity in dilute aqueous sodium hydroxide," Macromolecules, vol. 14, no. 5, pp. 1220-1225, Sep. 1981. https://doi.org/10.1021/ma50006a016

J. Kestin, H. E. Khalifa, and R. J. Correia, "Tables of the dynamic and kinematic viscosity of aqueous KCl solutions in the temperature range 25-150 °C and the pressure range 0.1-35 MPa," Journal of Physical and Chemical Reference Data, vol. 10, no. 1, pp. 57-70, Jan. 1981. https://doi.org/10.1063/1.555640

D. A. Elhossary, W. Alameri, and E. W. Al-Shalabi, "Experimental Investigation of Biopolymer Rheology and Injectivity in Carbonates," presented at the Offshore Technology Conference, Houston, Texas, USA, 2020. https://doi.org/10.4043/30680-MS

J. Fariña, F. Siñeriz, O. E. Molina, and N. I. Perotti, "Isolation and physicochemical characterization of soluble scleroglucan from Sclerotium rolfsii. Rheological properties, molecular weight and conformational characteristics," Carbohydrate Polymers, vol. 44, no. 1, pp. 41-50, Jan. 200. https://doi.org/10.1016/S0144-8617(00)00189-2

C. Noïk and J. Lecourtier, "Studies on scleroglucan conformation by rheological measurements versus temperature up to 150°C," Polymer, vol. 34, no. 1, pp. 150-157, Jan. 1993. https://doi.org/10.1016/0032-3861(93)90298-O

M. Grassi, R. Lapasin, and S. Pricl, "A study of the rheological behavior of scleroglucan weak gel systems," Carbohydrate Polymers, vol. 29, no. 2, pp. 169-181, Feb. 1996. https://doi.org/10.1016/0144-8617(95)00120-4

S. M. R. Quadri, M. Shoaib, A. M. AlSumaiti, and S. M. Alhassan, "Screening of Polymers for EOR in High Temperature, High Salinity and Carbonate Reservoir Conditions," presented at the International Petroleum Technology Conference, Doha, Qatar, 2015. https://doi.org/10.2523/IPTC-18436-MS

C. Gao, "Application of a novel biopolymer to enhance oil recovery," J Petrol Explor Prod Technol, vol. 6, no. 4, pp. 749-753, Dec. 2016. https://doi.org/10.1007/s13202-015-0213-7

Í. G. M. Silva and E. F. Lucas, "Rheological Properties of Xanthan Gum, Hydroxypropyl Starch, Cashew Gum and Their Binary Mixtures in Aqueous Solutions," Macromol. Symp., vol. 380, p. 1800070, 2018. https://doi.org/10.1002/masy.201800070

S. Wang, L. He, J. Guo, J. Zhao, and H. Tang, "Intrinsic viscosity and rheological properties of natural and substituted guar gums in seawater," International Journal of Biological Macromolecules, vol. 76, pp. 262-268, May 2015. https://doi.org/10.1016/j.ijbiomac.2015.03.002.

How to Cite
Clinckspoor, K. J., Ferreira, V. H. de S., & Moreno, R. B. Z. L. (2021). Bulk rheology characterization of biopolymer solutions and discussions of their potential for enhanced oil recovery applications. CT&F - Ciencia, Tecnología Y Futuro, 11(1), 123-135. https://doi.org/10.29047/01225383.367

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Published
2021-06-30
Section
Scientific and Technological Research Articles

Funding data

  • Shell
    Grant numbers ANP 20359-6
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