Corrosiveness of biodiesel obtained from different raw materials on gray cast iron
Keywords:
Corrosion, fatty acids, biodiesel
Abstract
The corrosive effects of biodiesel on gray cast iron at room temperature were studied. Static immersion tests were carried out through gravimetric techniques and in the absence of light, using five raw materials: beef tallow, lard, sunflower oil, soybean oil, and coconut oil. The influence of fatty acids that make up biodiesel was determined through linear regression with data obtained from the corrosion rate. Results show that biodiesels with a higher degree of unsaturated fats in their composition have a more significant effect on the loss of mass in the material, leading to more corrosive processes in gray cast iron.
References
Amaya, A. A., Piamba, O., & Olaya, J. (2014). Estudio de los efectos corrosivos del diésel y biodiésel sobre una fundición de hierro gris. R. Lat. Met. Mat., 34(2), 289-295.
Aktas, D., Lee, J., Little, B., Ray, R., Davidova, I., Lyles, C., & Suflita, J. (2010). Anaerobic metabolism of biodiesel and Its impact on metal corrosion. Energ. Fuel., 24 (5), 2924-2928. DOI: 10.1021/ef100084j.
ASM International. (1997). ASM Metals Handbook Volume 1 - Properties and Selection: Irons, steels, and high Perfomance alloys (10th ed.). The materials information company.
ASTM A48 (2014). Gray Iron Castings, ASTM Corrosion of Metals; Wear and erosion, Volume 03.02, ASTM International, West Conshohocken, PA.
ASTM D130 (2015) Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test, ASTM Petroleum Products, liquid fuels, and lubricants (I): C1234-D3710, Volume 05.01, ASTM International, West Conshohocken, PA.
ASTM G31 - Laboratory Immersion Corrosion Testing of Metals. ASTM Corrosion of Metals; Wear and Erosion, Volume 03.02, ASTM International, West Conshohocken, PA, 2014.
Bex, T. (1991). Chill testing: the effect of carbon equivalent. Mod. Cast., 83 (9), 59.
Biodisol. (2014). Energías alternativas, renovables, bioenergías.
Callister, W. (2002). Introducción a la Ciencia e Ingeniería de los Materiales. México: Reverté S.A.
Cardona M., D., González R., J., Rivera, M., & Cárdenas, E. (2013). Inferencia estadística Módulo de regresión lineal simple. Bogotá: Universidad del Rosario - Facultad de Administración.
Castiglioni, J. L. (2008). In Materiales ferrosos y sus aplicaciones., Buenos Aires: Universidad de Buenos Aires.
Christensen, E., & McCormick, R. (2014). Long-term storage stability of biodiesel and biodiesel blens. Fuel Process. Technol., 128: 339-348.
Da Silva. W., Salomao, A., Vila, M., & Tubino, M. (2016). Influence of water and ultraviolet irradiation on the induction period of the oxidation of biodiesel. J. Braz. Chem. Soc., 28 (4), 676-680. DOI: 10.5935/0103- 5053.20160201.
Fazal, M. A., Haseeb, A. S. M. A., & Masjuki, H. H. (2011). Effect of different corrosion inhibitors on the corrosion of cast iron in palm biodiesel. Fuel Process. Technol., 92(11), 2154–2159. http://dx.doi.org/10.1016/j. fuproc.2011.06.012.
Fazal, M. A., Haseeb, A. S. M. A., & Masjuki, H. H. (2012). Degradation of automotive materials in palm biodiesel. Energy, 40(1), 76–83. DOI: 10.1016/j.energy.2012.02.026.
Geller, D. P., Adams, T. T., Goodrum, J. W., & Pendergrass, J. (2008). Storage stability of poultry fat and diesel fuel mixtures: Specific gravity and viscosity. Fuel, 87(1), 92–102. DOI: http://dx.doi.org/10.1016/j.fuel.2007.03.043.
Grambow, B., & Revie, R. (2000). Uhlig´ s Corrosion Handbook. Uhlig´ s Corrosion Handbook. New Jersey: Wiley.
Haseeb, A. S. M. A., Fazal, M. A., Jahirul, M. I., & Masjuki, H. H. (2011). Compatibility of automotive materials in biodiesel: A review. Fuel, 90(3), 922–931.
Knothe, G., & Dunn, R. O. (2003). Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals. J. Amer. Oil Chem. Soc., 80(10), 1021–1026. DOI: 10.1007/s11746-003- 0814-x.
Knothe, G., Gerpen, J. Van, & Krahl, J. (2005). The Biodiesel Handbook. United States: AOCS Press.
Knothe, G. (2007). Some aspects of biodiesel oxidative stability. Fuel Process. Technol., 88 (7), 669-677. DOI: http://dx.doi.org/10.1016/j.fuproc.2007.01.005.
Kyriakidis, N. B., & Katsiloulis, T. (2000). Calculation of iodine value from measurements of fatty acid methyl esters of some oils: Comparison with the relevant American oil chemists society method. J. Amer. Oil Chem. Soc., 77(12), 1235–1238. DOI: 10.1007/s11746-000-0193-3.
McCormick, R., Ratcliff, M., Moens, L., & Lawrence, R. (2007) Several factors affecting the stability of biodiesel in standard accelerated test, Fuel Process. Technol., 88 (7), 651-657. DOI: http://dx.doi.org/10.1016/j.fuproc.2007..01.006.
Piamba, O. (2009). Estudo do desempenho do grupo motor-gerador alimentado com diferentes misturas diesel-biocombustíveis e avaliação de emissões. Tese de Doutorado Esc. De Engenharia, Universidade Federal Fluminense, Niterói, Brasil, 214pp.
Singh, B., Korstad, J., & Sharma, Y. C. (2012). A critical review on corrosion of compression ignition (CI) engine parts by biodiesel and biodiesel blends and its inhibition. Renew. Sust. Energy Rev., 16(5), 3401–3408. DOI: http://dx.doi. org/10.1016/j.rser.2012.02.042.
Sorensen, G., Pedersen, D., Nørgaard, A., Sørensen, K., & Nygaard, S. (2011). Microbial growth studies in biodiesel blends. Biores. Technol., 102 (8), 5259–5264.
Tsuchiya, T., Shiotani, H., Goto, S., Sugiyama, G., & Maeda, A. (2006). Japanese Standards for diesel fuel containing 5% FAME: Investigation of acid generation in FAME blended diesel fuels and Its impact on corrosion. SAE Techn. Papers Ser. DOI: http://doi.org/10.4271/2006-01-3303.
Waynick, J. (2005) Characterization of Biodiesel Oxidation and Oxidation Products, Crc Project No. Avfl-2b. National Renewable Energy Laboratory U.S. Department of Energy.
Aktas, D., Lee, J., Little, B., Ray, R., Davidova, I., Lyles, C., & Suflita, J. (2010). Anaerobic metabolism of biodiesel and Its impact on metal corrosion. Energ. Fuel., 24 (5), 2924-2928. DOI: 10.1021/ef100084j.
ASM International. (1997). ASM Metals Handbook Volume 1 - Properties and Selection: Irons, steels, and high Perfomance alloys (10th ed.). The materials information company.
ASTM A48 (2014). Gray Iron Castings, ASTM Corrosion of Metals; Wear and erosion, Volume 03.02, ASTM International, West Conshohocken, PA.
ASTM D130 (2015) Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test, ASTM Petroleum Products, liquid fuels, and lubricants (I): C1234-D3710, Volume 05.01, ASTM International, West Conshohocken, PA.
ASTM G31 - Laboratory Immersion Corrosion Testing of Metals. ASTM Corrosion of Metals; Wear and Erosion, Volume 03.02, ASTM International, West Conshohocken, PA, 2014.
Bex, T. (1991). Chill testing: the effect of carbon equivalent. Mod. Cast., 83 (9), 59.
Biodisol. (2014). Energías alternativas, renovables, bioenergías.
Callister, W. (2002). Introducción a la Ciencia e Ingeniería de los Materiales. México: Reverté S.A.
Cardona M., D., González R., J., Rivera, M., & Cárdenas, E. (2013). Inferencia estadística Módulo de regresión lineal simple. Bogotá: Universidad del Rosario - Facultad de Administración.
Castiglioni, J. L. (2008). In Materiales ferrosos y sus aplicaciones., Buenos Aires: Universidad de Buenos Aires.
Christensen, E., & McCormick, R. (2014). Long-term storage stability of biodiesel and biodiesel blens. Fuel Process. Technol., 128: 339-348.
Da Silva. W., Salomao, A., Vila, M., & Tubino, M. (2016). Influence of water and ultraviolet irradiation on the induction period of the oxidation of biodiesel. J. Braz. Chem. Soc., 28 (4), 676-680. DOI: 10.5935/0103- 5053.20160201.
Fazal, M. A., Haseeb, A. S. M. A., & Masjuki, H. H. (2011). Effect of different corrosion inhibitors on the corrosion of cast iron in palm biodiesel. Fuel Process. Technol., 92(11), 2154–2159. http://dx.doi.org/10.1016/j. fuproc.2011.06.012.
Fazal, M. A., Haseeb, A. S. M. A., & Masjuki, H. H. (2012). Degradation of automotive materials in palm biodiesel. Energy, 40(1), 76–83. DOI: 10.1016/j.energy.2012.02.026.
Geller, D. P., Adams, T. T., Goodrum, J. W., & Pendergrass, J. (2008). Storage stability of poultry fat and diesel fuel mixtures: Specific gravity and viscosity. Fuel, 87(1), 92–102. DOI: http://dx.doi.org/10.1016/j.fuel.2007.03.043.
Grambow, B., & Revie, R. (2000). Uhlig´ s Corrosion Handbook. Uhlig´ s Corrosion Handbook. New Jersey: Wiley.
Haseeb, A. S. M. A., Fazal, M. A., Jahirul, M. I., & Masjuki, H. H. (2011). Compatibility of automotive materials in biodiesel: A review. Fuel, 90(3), 922–931.
Knothe, G., & Dunn, R. O. (2003). Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals. J. Amer. Oil Chem. Soc., 80(10), 1021–1026. DOI: 10.1007/s11746-003- 0814-x.
Knothe, G., Gerpen, J. Van, & Krahl, J. (2005). The Biodiesel Handbook. United States: AOCS Press.
Knothe, G. (2007). Some aspects of biodiesel oxidative stability. Fuel Process. Technol., 88 (7), 669-677. DOI: http://dx.doi.org/10.1016/j.fuproc.2007.01.005.
Kyriakidis, N. B., & Katsiloulis, T. (2000). Calculation of iodine value from measurements of fatty acid methyl esters of some oils: Comparison with the relevant American oil chemists society method. J. Amer. Oil Chem. Soc., 77(12), 1235–1238. DOI: 10.1007/s11746-000-0193-3.
McCormick, R., Ratcliff, M., Moens, L., & Lawrence, R. (2007) Several factors affecting the stability of biodiesel in standard accelerated test, Fuel Process. Technol., 88 (7), 651-657. DOI: http://dx.doi.org/10.1016/j.fuproc.2007..01.006.
Piamba, O. (2009). Estudo do desempenho do grupo motor-gerador alimentado com diferentes misturas diesel-biocombustíveis e avaliação de emissões. Tese de Doutorado Esc. De Engenharia, Universidade Federal Fluminense, Niterói, Brasil, 214pp.
Singh, B., Korstad, J., & Sharma, Y. C. (2012). A critical review on corrosion of compression ignition (CI) engine parts by biodiesel and biodiesel blends and its inhibition. Renew. Sust. Energy Rev., 16(5), 3401–3408. DOI: http://dx.doi. org/10.1016/j.rser.2012.02.042.
Sorensen, G., Pedersen, D., Nørgaard, A., Sørensen, K., & Nygaard, S. (2011). Microbial growth studies in biodiesel blends. Biores. Technol., 102 (8), 5259–5264.
Tsuchiya, T., Shiotani, H., Goto, S., Sugiyama, G., & Maeda, A. (2006). Japanese Standards for diesel fuel containing 5% FAME: Investigation of acid generation in FAME blended diesel fuels and Its impact on corrosion. SAE Techn. Papers Ser. DOI: http://doi.org/10.4271/2006-01-3303.
Waynick, J. (2005) Characterization of Biodiesel Oxidation and Oxidation Products, Crc Project No. Avfl-2b. National Renewable Energy Laboratory U.S. Department of Energy.
How to Cite
Castro, J. D., Piamba, O. E., & Olaya, J. J. (2016). Corrosiveness of biodiesel obtained from different raw materials on gray cast iron. CT&F - Ciencia, Tecnología Y Futuro, 6(4), 79–88. https://doi.org/10.29047/01225383.05
Downloads
Download data is not yet available.
Published
2016-12-15
Issue
Section
Scientific and Technological Research Articles
