A simulator for the study of phase behaviour based on the SOAVE equation of state and material balance calculations.

  • C. V. PELAEZ Ecopetrol S.A. – Instituto Colombiano del Petróleo, A.A. 4185 Bucaramanga, Santander, Colombia
  • J. C. M. ESCOBAR Ecopetrol S.A. – Instituto Colombiano del Petróleo, A.A. 4185 Bucaramanga, Santander, Colombia
Keywords: equations of state (EDE), volume translation, characterisation, material balance, process simulation

Abstract

This paper shows the predictive features, speed and accuracy of a phase behavior simulator which calculates and analyzes the vapor-liquid equilibrium of volatile oils and gas condensates. The simulator calculates the PVT properties (gas volumetric factor (Bg), oil volumetric factor (Bo), gas/ oil ratios (Rso, Rsg) required by reservoir simulators and used in two-phase flow equations and reservoir material balances.The model uses the Soave-Redlich-Kwong equation of state (SRK-EOS) to predict phase behavior without any parameter adjustment. lt only utilizes the concept of volume translation and a simple C7+ characterization. A rigorous material balance checks the consistency of  the measured PVT data and· calculates properties such as: liquid composition at different pressures, K values, molecular weight, liquid densities and PVT properties, among others. The C7+ characterization method used by the simulator was compared to that presented by Pedersen et al. (1984). The CPU time in the constant volume depletion test (CVD) was significantly reduced (up to 80%) by using the simple C1+ characterization method.

References

Ahmed, T.,1991. "A Practical Equation ofState", SPERE, (feb): 137 - 146. https://doi.org/10.2118/18532-PA

Bashbush, J.L., 1981. "A Method to Determine K-Values fom Laboratory Data and Its Aplications", SPE 10.127 presentado en la Reunión Anual de Otoño del SPE, San Antonio, Texas, October; 5 - 7. https://doi.org/10.2118/10127-MS

Boe, A., Skjaeveland, S.M. yWhitson, C. H., 1981, "Ttwo­ Phase Pressure Test Analysis", SPE 10.224 presentado en la reunión anual de Otoño delSPE, San Antonio, Texas , October; 5 - 7.

Chien, M.C. H.yMonroy, M. R., 1986, "Two New Density Correlations", SPE 15.676 present ado en la conferencia técnica anual del SPE, New Orleans, LA, October; 5 - 8. https://doi.org/10.2118/15676-MS

Da Silva, M . B. y Rodríguez, F., 1992 "Automatic Fitting of Equations of State for Phase Behavior Maching", SPE paper 23.703 presented at !heSPE Second Latin American Petroleum Eng. Conference in Caracas, March, 8 - 11. https://doi.org/10.2118/23703-MS

Firoozabadi, A. , 1988. "Reservoir-Fluid Phase Behavior and Volumetric Prediction With EOS", Journal of Petroleum Teclmology. (Apr il).

Jha veri , B. S . y Youngren, G. K., 1988. "T hree-Parameter Modification of !he Peng-Robinson Equation of State To Improve Volumetric Preclictions", SPE Reservoir Engi­ neering (August) . https://doi.org/10.2118/13118-PA

Knudsen, K. , Stenby, E. H. y Muller, M. A., 1992. " Ther­ modynamic Model for Evaluation of Equilibrium Between Fluids from Diferent Parts of A Reservoir" , Int Energy Agency Collab Proj Enhanced Oil Recovery. lnt Symp Pap No. 11.

Li, Y. K.• Nghiem, L. X. y Siu, A., 1985. " Pilase Behavior Computations for Reservoir Fluids: effect of pseudo­ components on phase diagrams and simulations results'' , JCPT (Nov - Dec): 29 - 36. https://doi.org/10.2118/85-06-02

Lira-Galeana, C., Ponce-Ramírez, L. y García-Sánchez, F., 1992, "A Molecular Thennody namic Approach to the Prediction of Phase Equilibria in Reservoir Simulation", Can. J. Chem. Eng, 70 (June): 559 - 568. https://doi.org/10.1002/cjce.5450700320

Martín, J. J., 1967. "Equations of State", lnd. Eng. Chem., 59 (12) . https://doi.org/10.1021/ie50696a008

Mohammed, S. A. yWattenbarger, R. A., 1991. "A Simpli­ fied Method for Computing Phase Behavior of Carbon Dioxide/Hydrocarbon Mixtures in Compositional Simu­ lation", SPE paper 21430 presented at the SPE Midle East Oil Show Held in Bahrain, November, 16 -19. https://doi.org/10.2118/21430-MS

Peneloux, A., Rauzy, E. y Freze, R., 1982. "A Consistent Correction for Redlich - Kwong -Soave Volwnes", Fluid Phase Equilibria, 8. https://doi.org/10.1016/0378-3812(82)80002-2

Pedersen, K. S., Thomassen, P. y Fredenslund, A., 1984. "Thermodynamics of Petroleum Mixtures Containing. Heavy Hydrocarbons . 1. Phase Envelope Calculations by useof the Soave - Redlich - Kwong Equation of State", Ind. Eng. Chem. Proc. Des. Dev., (23): 163 - 170. https://doi.org/10.1021/i200024a027

Reid, R., Prausnitz, J. M. y Sherwood, T., 1977. The Proper­ ty o/Gases and Liquids, 3rd ed, McGraw - Hill, p. 21.

Riazi, M.R. yDaubert, T. E., 1987. "CharacterizationPara­ meter for Petroleum Fractions", Ind. Eng. Chem. Res., (26): 755"0 759. https://doi.org/10.1021/ie00064a023

Rojas, G. y Requena, O., 1992. "A New Method to Estimate Compressibility Factors for CO2 Hydrocarbon Mixtures", SPE paper 23661 presente.d at the SPE Second Latin American Petroleum Eng. Conference in Caracas, march, 8 - 11. https://doi.org/10.2118/23661-MS

Spencér, C.F., y Danner, R.P., 1972. "Improved Equation for Prediction of Satured Liquid Density", Journal of Chemical and Engineering Data, 17 ( 2). https://doi.org/10.1021/je60053a012

Soave, R. C., 1972. "Equilibrium Constants from a Modified Redlich - Kwong Equation of State", Chem. Eng. Sci., (27): 1197 - 1203. https://doi.org/10.1016/0009-2509(72)80096-4

Soreide, I., 1989. "Improved Phase Behavior Prediction of Petrolewn Reservoir Fluids From A Cubic Equation of State", Dr. Techn. Thesis Norwegian lnstitute of . Technology, Department of Petroleum Engineering.

Whitson, C. H. y Torp, S. B., 1983. "Evaluating Constant Volume Depletion Data", JPT, (March). https://doi.org/10.2118/10067-PA

Whitson, C. H., 1983. "Caracterizing Hydrocarbon Plus Frac tions" . SPEJ(Augt.): 683-694; Trans., AIME, 275. https://doi.org/10.2118/12233-PA

Whitson, C. H., 1984. "Effect of C7+ Properties on Equation of State Predictions", SPEJ, (Dic.): 685-696, Trans. AIME, 277 . https://doi.org/10.2118/11200-PA

Whitson, C. H., Anderson, T. F. y Soreide, I., 1988. "C7+ Characterization ofRelated Equilibrium Fluids Using the Gamma Distribution", Paper presented a the AIChE Spring Meeting, New Orleans, March 6 - 10.

Xu, D. H., Danesh, A. y Todd, A. C., 1992. "An Accelerated Successive Substitution Method for Calculation of Saturation Pressure of Multicomponent Fluids" , Fluid Phase Equilibria, 72, 15 - 24. https://doi.org/10.1016/0378-3812(92)85016-2

How to Cite
PELAEZ, C. V. ., & M. ESCOBAR, J. C. . (1995). A simulator for the study of phase behaviour based on the SOAVE equation of state and material balance calculations. CT&F - Ciencia, Tecnología Y Futuro, 1(1), 83–94. https://doi.org/10.29047/01225383.609

Downloads

Download data is not yet available.
Published
1995-12-31
Section
Scientific and Technological Research Articles

Altmetric

Crossref Cited-by logo
QR Code